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Application of Oxidized Polyethylene Wax in Coatings and Inks Industry
  • Description

In the dynamic landscape of the coatings and inks industry, the pursuit of enhanced product performance, durability, and aesthetic appeal drives continuous innovation. Oxidized polyethylene wax, a versatile additive with unique chemical and physical properties, has emerged as a key player in this realm. Its application in coatings and inks offers a multitude of benefits, significantly influencing the quality and functionality of the final products.

Understanding Oxidized Polyethylene Wax

Oxidized polyethylene wax is a modified form of polyethylene wax, obtained through a controlled oxidation process. This process introduces polar functional groups, such as carboxyl and hydroxyl groups, onto the polyethylene backbone. These functional groups endow the wax with excellent compatibility with various binders, solvents, and pigments commonly used in coatings and inks.
Oxidized polyethylene wax boasts properties like high melting point (usually between 100 – 120°C), low viscosity, and superior thermal stability. These characteristics make it an ideal additive for formulating high – performance coatings and inks, as it can withstand the processing conditions and contribute to the overall performance of the final products.
Fig. 1 Chemical Structure of Oxidized Polyethylene Wax
Fig. 2 Manufacturing Process of Oxidized Polyethylene Wax

Applications in the Coatings Industry

Scratch and Abrasion Resistance

One of the primary applications of oxidized polyethylene wax in coatings is to enhance scratch and abrasion resistance. When incorporated into the coating formulation, the wax particles form a protective layer on the surface of the coating film. As external forces, such as friction or scratching, act on the coated surface, these wax particles act as a barrier, reducing the likelihood of surface damage.
In automotive coatings, for example, the addition of oxidized polyethylene wax can significantly improve the scratch resistance of the paint. A study showed that coatings with 3 – 5% of oxidized polyethylene wax had a 40% increase in scratch resistance compared to those without the additive. This not only prolongs the aesthetic life of the vehicle but also protects the underlying substrate.
Fig. 3 Scratch Resistance Test of Coating with Oxidized Polyethylene Wax

Anti – Blocking and Anti – Marring

Coatings often need to be stacked or rolled up during storage or transportation. Without proper anti – blocking agents, the coated surfaces can stick together, causing damage when separated. Oxidized polyethylene wax provides excellent anti – blocking properties by creating a micro – rough surface texture. This texture reduces the contact area between coated surfaces, preventing them from adhering to each other.
Similarly, in applications where the coated surface may come into contact with other objects, such as furniture or flooring coatings, anti – marring properties are crucial. Oxidized polyethylene wax helps to minimize the formation of marks or scratches caused by such contact, maintaining the appearance of the coated surface.

Gloss and Surface Smoothness

The addition of oxidized polyethylene wax can also significantly impact the gloss and surface smoothness of coatings. As the wax particles migrate to the surface during the drying process of the coating, they contribute to a more uniform and smooth surface. This results in enhanced gloss, making the coated product more visually appealing.
In architectural coatings, a high – gloss finish is often desired for decorative purposes. Oxidized polyethylene wax enables formulators to achieve the desired gloss levels while also improving the overall surface quality of the coating.

Applications in the Inks Industry

Pigment Dispersion

Inks rely on the uniform dispersion of pigments to achieve consistent color and print quality. Oxidized polyethylene wax acts as an effective dispersant, helping to break down pigment agglomerates and keep the pigments well – dispersed in the ink medium.
The polar functional groups of the wax interact with both the pigments and the ink binders, reducing the surface tension between them. This facilitates the wetting of pigments by the ink vehicle, ensuring that the pigments are evenly distributed throughout the ink. As a result, inks formulated with oxidized polyethylene wax exhibit better color strength, color uniformity, and printability.
Fig. 4 Pigment Dispersion Process in Ink with Oxidized Polyethylene Wax

Rub Resistance

In many printing applications, such as labels and packaging, the printed ink needs to withstand rubbing and abrasion during handling, storage, and transportation. Oxidized polyethylene wax improves the rub resistance of inks by forming a protective layer on the printed surface.
When the printed material is subjected to rubbing, the wax layer reduces the friction between the printed surface and the contacting object, preventing the ink from smudging or wearing off. This is particularly important for inks used in high – traffic applications, where maintaining the integrity of the printed image is essential.

Anti – Foaming

During the ink manufacturing process and printing operations, foam can form, which can negatively affect the quality of the ink and the printing process. Oxidized polyethylene wax has anti – foaming properties, which help to break down and prevent the formation of foam.
The wax disrupts the surface tension of the foam bubbles, causing them to collapse. This ensures a smooth and consistent ink flow during printing, reducing the occurrence of printing defects caused by foam.

Case Studies

Coating for Wood Furniture

A leading wood furniture manufacturer incorporated oxidized polyethylene wax into their top – coat formulation. The resulting coating not only had a high – gloss finish but also showed remarkable scratch and mar resistance. The furniture pieces were able to withstand the rigors of handling and transportation without significant surface damage, leading to increased customer satisfaction and reduced warranty claims.

Flexographic Printing Ink

A packaging printing company used inks formulated with oxidized polyethylene wax for printing on flexible packaging materials. The inks demonstrated excellent pigment dispersion, resulting in vibrant and consistent colors. Moreover, the printed packaging had enhanced rub resistance, ensuring that the printed images remained intact even after multiple handling and storage cycles.

Conclusion

Oxidized polyethylene wax has proven to be an invaluable additive in the coatings and inks industry. Its ability to improve scratch and abrasion resistance, enhance pigment dispersion, and provide various other functional benefits makes it an essential component in formulating high – performance products. As the demand for coatings and inks with better performance, durability, and environmental friendliness continues to grow, the role of oxidized polyethylene wax is likely to become even more significant. Future research and development efforts are expected to further explore and optimize the use of this versatile additive, opening up new possibilities for innovation in the coatings and inks industry.
 
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